I've scanned the wiki and i'm still a bit confused about how the defenses on gear works.
does the defense on armor/helm/shield stack?
does the defense on the shield only matter when actually blocking?
i may have more after these two, but for now we'll start with these.
The defense stats on your shield only apply when you're blocking.
UVs like attack speed increased, like on the Swiftstrike Buckler, apply even if you're not blocking.
The stats on your armor and helm do stack.
If you go look at the Spiral Knights Wiki there's a TON of information, as well as pictures, about this stuff.