Well, I've been browsing the arsenal forums recently and I noticed that these sets have a bit of hate because people think they're useless but in reality they're not useless at all. It's true that they're specialised sets which means that they have specific usages but that doesn't mean they're entirely useless. So I'll give you some ideas on how they should be used.
Volcanic Salamander
Would work great at C42 and places with lots of oilers since oilers when lit on fire deal some elemental damage as well as their fire status. Also, most slime levels have a lot of constructs in them. This includes JK and IQ as well as lichenous lairs and jelly farms. These places have a lot of gun puppies and lumbers usually.
Arcane Salamander
Works in the same places as Volcanic Salamander while being slightly better as lichenous lairs as they include beasts as well. They also work in jelly farms where there are not only jelly cubes but also lumbers, gun puppies, lizards and wolvers. Another use for it is in FSC where there are some slimes and wolvers though little. You would be able to damage them while still having elemental defense for fire puppies and fire defense for the whole level.
There are currently no class armor sets that provide weapon damage increase and normal defense together so these may actually work a fair bit in this aspect if you mostly play fire levels with many weapon types. Of course Vog Cub and Volcanic Demo work too, but if you already have much ASI/CTR from Swiftstrike Buckler or unique variants these will serve you pretty well. You may also pair them with these sets if you have like high ASI/CTR for optimization's sake. There's not a single useless equipment piece in this game. It's true that some sets are good overall but when it comes to certain situations they fall short. Even Black Kat and Chaos seem almost useless in C42 when compared to Dragon Scale which is considered one of the weakest sets in the game overall.
oilers when lit on fire deal some elemental damage as well as their fire status
Ingited oilers deal elemental and fire? That's news to me. Can someone else verify? I've always thought that they deal piercing and fire.
To make a case for Volcanic Salamander, we're looking for a place that's filled with slimes, where the monsters deal elemental damage. Yes, slimes are often accompanied by constructs (because constructs are everywhere), so elemental defense is not too bad. But piercing is the main damage on a slime level. So how many players are going to invest in this specialized mix? As a newbie I would rather have Vog Cub or Seerus. As an experienced knight I would rather have Chaos or Black Kat with status UVs.
Arcane Salamander...Works in the same places as Volcanic Salamander while being slightly better as lichenous lairs as they include beasts as well.
Compared to Volcanic, you lose some slime damage for the sake of beast damage. And lichenous lairs are mainly filled with slimes. So Arcane is not "slightly better", damage-wise, in this situation. And beasts are so pitifully easy that every knight should be going into beast-heavy levels with glass cannon armor anyway.
In summary, I like that you're trying to find the niches for these armors, but I don't think that you've found any yet.