It is perfectly reasonable that any item whose alchemy origin is below 4 stars becomes auto-bound when crafted to that point or beyond. However it's a little weird for items that already start that high. So:
If an alchemy path STARTS at 4 stars (such as the Stone Tortoise), allow the 4 star item to remain unbound unless it is upgraded to its 5 star form, in which case the 5 star form will auto-bind when crafted (such as upgrading Stone Tortoise to Omega Shell).
If an alchemy path STARTS at 5 stars (such as the Heater Shield), allow the 5 star item to remain unbound.